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Issue 31, 2018
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Two catalytic protocols for Achmatowicz rearrangement using cyclic diacyl peroxides as oxidants

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Abstract

In situ generated bromonium-catalyzed and visible-light photocatalytic Achmatowicz rearrangements of furfuryl alcohols using cyclic diacyl peroxides as oxidants are described. Both protocols feature broad substrate scope, excellent functional group tolerance, and mild reaction conditions, affording the synthetically useful dihydropyranone derivatives in good yields.

Graphical abstract: Two catalytic protocols for Achmatowicz rearrangement using cyclic diacyl peroxides as oxidants

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Publication details

The article was received on 12 Jun 2018, accepted on 16 Jul 2018 and first published on 17 Jul 2018


Article type: Communication
DOI: 10.1039/C8OB01382A
Citation: Org. Biomol. Chem., 2018,16, 5566-5569
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    Two catalytic protocols for Achmatowicz rearrangement using cyclic diacyl peroxides as oxidants

    C. Wei, R. Zhao, Z. Shen, D. Chang and L. Shi, Org. Biomol. Chem., 2018, 16, 5566
    DOI: 10.1039/C8OB01382A

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