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Issue 28, 2018
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Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

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Abstract

Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at a low oxidation potential in the presence of a nucleophile. The application of this concept is demonstrated for the allylation of carbenium ions generated by the anodic oxidation of stannylmethylethers.

Graphical abstract: Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

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Publication details

The article was received on 07 Jun 2018, accepted on 27 Jun 2018 and first published on 27 Jun 2018


Article type: Communication
DOI: 10.1039/C8OB01339J
Citation: Org. Biomol. Chem., 2018,16, 5094-5096
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    Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

    A. Lielpetere and A. Jirgensons, Org. Biomol. Chem., 2018, 16, 5094
    DOI: 10.1039/C8OB01339J

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