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Issue 27, 2018
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Facile and practical synthesis of β-carbolinium salts and γ-carbolinium salts via rhodium-catalyzed three-component reactions

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Abstract

A facile and practical [Cp*RhCl2]2-catalyzed three-component reaction between indolyl aldehydes, amines and alkynes involving C–H activation and cyclization has been developed. A series of β-carbolinium salts and γ-carbolinium salts are successfully afforded in good to quantitative yields under mild conditions. This efficient and convergent strategy provides a good choice for constructing the libraries of β-carbolinium salts and γ-carbolinium salts.

Graphical abstract: Facile and practical synthesis of β-carbolinium salts and γ-carbolinium salts via rhodium-catalyzed three-component reactions

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Publication details

The article was received on 19 May 2018, accepted on 20 Jun 2018 and first published on 20 Jun 2018


Article type: Paper
DOI: 10.1039/C8OB01182F
Citation: Org. Biomol. Chem., 2018,16, 5021-5026
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    Facile and practical synthesis of β-carbolinium salts and γ-carbolinium salts via rhodium-catalyzed three-component reactions

    Z. Wang, T. Li, S. Xing and B. Zhu, Org. Biomol. Chem., 2018, 16, 5021
    DOI: 10.1039/C8OB01182F

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