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Issue 27, 2018
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Second-order asymmetric transformation and its application for the practical synthesis of α-amino acids

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Abstract

We report a discovery of a new rimantadine [1-(1-adamantyl)ethanamine]-derived chiral ligand and its application for the preparation of α-amino acids using the second-order asymmetric transformation approach. The operational ease of experimental procedures coupled with excellent chemical yields and stereochemical outcome suggests some potential synthetic generality of this approach.

Graphical abstract: Second-order asymmetric transformation and its application for the practical synthesis of α-amino acids

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Publication details

The article was received on 26 Apr 2018, accepted on 19 Jun 2018 and first published on 19 Jun 2018


Article type: Communication
DOI: 10.1039/C8OB00963E
Citation: Org. Biomol. Chem., 2018,16, 4968-4972
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    Second-order asymmetric transformation and its application for the practical synthesis of α-amino acids

    R. Takeda, A. Kawamura, A. Kawashima, T. Sato, H. Moriwaki, K. Izawa, H. Abe and V. A. Soloshonok, Org. Biomol. Chem., 2018, 16, 4968
    DOI: 10.1039/C8OB00963E

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