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A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates

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Abstract

A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates was developed under mild conditions, providing two distinct products in good yields. Compared to decarboxylative addition-Brook rearrangement, the decarboxylative addition products could be controlled by using a simple bifunctional organocatalyst thiourea derivative instead of DABCO. This new reaction model of silyl glyoxylates offered a facile and alternative route to organosilicon compounds.

Graphical abstract: A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates

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Publication details

The article was received on 29 Mar 2018, accepted on 10 May 2018 and first published on 10 May 2018


Article type: Paper
DOI: 10.1039/C8OB00740C
Citation: Org. Biomol. Chem., 2018, Advance Article
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    A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates

    M. Han, H. Pan, J. Lin, W. Li, P. Li and L. Wang, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB00740C

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