Issue 8, 2018

Intramolecular Morita–Baylis–Hillman reaction as a strategy for the construction of tricyclic sesquiterpene cores

Abstract

Starting from a common polyfunctionalized bicyclo[3.2.1]octane-6,8-dione intermediate, a concise synthetic route to tricyclic cores found in quadrane, suberosane, cedrane and related sesquiterpenes was developed using a Morita–Baylis–Hillman intramolecular reaction as a key step.

Graphical abstract: Intramolecular Morita–Baylis–Hillman reaction as a strategy for the construction of tricyclic sesquiterpene cores

Supplementary files

Article information

Article type
Paper
Submitted
18 Dec 2017
Accepted
30 Jan 2018
First published
30 Jan 2018

Org. Biomol. Chem., 2018,16, 1381-1389

Intramolecular Morita–Baylis–Hillman reaction as a strategy for the construction of tricyclic sesquiterpene cores

C. Peter, P. Geoffroy and M. Miesch, Org. Biomol. Chem., 2018, 16, 1381 DOI: 10.1039/C7OB03124F

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