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Dendronised diazapyrenium derivatives: host–guest complexes in aqueous solution

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Abstract

Dendronised diazapyrenium derivatives were synthesised with glycol-appended dendrons to confer water solubility. These dendrimers form self-assembled supramolecular structures with cucurbituril hosts. The self-assembly process could be monitored by changes in the absorption spectra and redox properties of the dendrimers due to electronic interactions of the electron-accepting diazapyrenium core with the electron-rich inner cavity of cucurbiturils.

Graphical abstract: Dendronised diazapyrenium derivatives: host–guest complexes in aqueous solution

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Publication details

The article was received on 31 Jul 2018, accepted on 04 Sep 2018 and first published on 12 Sep 2018


Article type: Paper
DOI: 10.1039/C8NJ03828G
Citation: New J. Chem., 2018, Advance Article
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    Dendronised diazapyrenium derivatives: host–guest complexes in aqueous solution

    J. K. Molloy, G. Bergamini, M. Baroncini, U. Hahn and P. Ceroni, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ03828G

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