Jump to main content
Jump to site search

Issue 19, 2018
Previous Article Next Article

Synthesis and properties of phosphorus and sulfur co-doped graphene

Author affiliations

Abstract

The derivatisation of graphene significantly extends its application potential beyond just a highly conductive material. The introduction of sulfur based functionalities is relatively difficult and remains quite unexplored. Here, we demonstrated effective functionalization of graphene oxide with sulfur and phosphorus based functionalities by a simple one step reaction using phosphorus(V) sulfide known in organic synthesis as the Berzelius reagent. The chemistry of the starting graphene oxide significantly influenced the degree of functionalization. A detailed chemical analysis of the modified graphene showed the presence of various sulfur based functional groups as well as thiophosphate derivatisation. The resulting graphene highly functionalized with thiol based groups proved to be an effective immobilizer for gold nanoparticles.

Graphical abstract: Synthesis and properties of phosphorus and sulfur co-doped graphene

Back to tab navigation

Supplementary files

Publication details

The article was received on 03 Jul 2018, accepted on 21 Aug 2018 and first published on 24 Aug 2018


Article type: Paper
DOI: 10.1039/C8NJ03321H
Citation: New J. Chem., 2018,42, 16093-16102
  •   Request permissions

    Synthesis and properties of phosphorus and sulfur co-doped graphene

    M. Lojka, O. Jankovský, D. Sedmidubský, V. Mazánek, D. Bouša, M. Pumera, S. Matějková and Z. Sofer, New J. Chem., 2018, 42, 16093
    DOI: 10.1039/C8NJ03321H

Search articles by author

Spotlight

Advertisements