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Issue 17, 2018
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New thiophene-based C60 fullerene derivatives as efficient electron transporting materials for perovskite solar cells

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Abstract

The synthesis of new C60 fullerene derivatives functionalized with thiophene moieties as well as with electron donating or electron withdrawing groups, bromine (Br) or cyano (CN), respectively, using Bingel reactions is reported. The synthesized derivatives were used as the electron transporting materials (ETMs) in inverted perovskite solar cells (PSCs). Compared to devices fabricated with [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM), the new derivatives showed similar electrochemical properties and electron mobilities. However, PSCs based on the new derivatives synthesized in this work exhibited higher power conversion efficiencies (PCEs) than PC61BM based devices, which were ascribed to their better passivation ability, likely due to specific interactions between the fullerene addend and the perovskite layer surface. Devices based on the fullerene bearing the CN group exhibited an additionally improved efficiency due to the increased dielectric constant (εr) of this derivative. These results show that the new functionalized fullerene derivatives can act as efficient ETMs in inverted PSCs.

Graphical abstract: New thiophene-based C60 fullerene derivatives as efficient electron transporting materials for perovskite solar cells

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Publication details

The article was received on 20 Jun 2018, accepted on 30 Jul 2018 and first published on 30 Jul 2018


Article type: Paper
DOI: 10.1039/C8NJ03067G
Citation: New J. Chem., 2018,42, 14551-14558
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    New thiophene-based C60 fullerene derivatives as efficient electron transporting materials for perovskite solar cells

    E. Castro, O. Fernandez-Delgado, F. Arslan, G. Zavala, T. Yang, S. Seetharaman, F. D'Souza and L. Echegoyen, New J. Chem., 2018, 42, 14551
    DOI: 10.1039/C8NJ03067G

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