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Issue 18, 2018
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Unprecedented photosensitivity of heterotrimetallic copper(II)/sodium/mercury(II) coordination polymer based thin film semiconductor device

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Abstract

A hetero-polynuclear complex, [{CuLNa}2(μ-1,1,3-NCS)HgCl(μ-Cl)(μ-1,3-NCS)]n {H2L = N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine}, has been synthesized and characterized. The estimated optical band gap indicates that the complex belongs to the semiconductor family. The photosensitivity of the complex is also very high (∼57). This complex finds application in the fabrication of a Schottky barrier diode.

Graphical abstract: Unprecedented photosensitivity of heterotrimetallic copper(ii)/sodium/mercury(ii) coordination polymer based thin film semiconductor device

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Publication details

The article was received on 08 May 2018, accepted on 16 Jul 2018 and first published on 17 Aug 2018


Article type: Paper
DOI: 10.1039/C8NJ02261E
Citation: New J. Chem., 2018,42, 15295-15305
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    Unprecedented photosensitivity of heterotrimetallic copper(II)/sodium/mercury(II) coordination polymer based thin film semiconductor device

    S. Roy, S. Halder, M. G. B. Drew, P. P. Ray and S. Chattopadhyay, New J. Chem., 2018, 42, 15295
    DOI: 10.1039/C8NJ02261E

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