Jump to main content
Jump to site search


A novel facile transformation to 1,2-bis(3-nitro-1-(1H-tetrazol-5-yl)-1H-1,2,4-triazol-5-yl)hydrazine salts

Author affiliations

Abstract

A novel high-nitrogen compound, 1,2-bis(3-nitro-1-(1H-tetrazol-5-yl)-1H-1,2,4-triazol-5-yl)diazene, was designed and synthesized. The corresponding hydrazine energetic salts were prepared through spontaneous reductive conversion by structurally varied amino salts. All energetic salts showed good thermal stabilities with decomposition temperatures ranging from 212 to 259 °C, and high positive heats of formation in the range of 411.1 to 1554.7 kJ mol−1. Furthermore, hydroxyammonium salt featured a promising integrated energetic performance (vD = 9038 m s−1, IS = 8 J, and FS = 360 N), which is superior to that of RDX (vD = 8890 m s−1, IS = 7.4 J, FS = 120 N), showing promising properties for new high-nitrogen high-energy-density materials.

Graphical abstract: A novel facile transformation to 1,2-bis(3-nitro-1-(1H-tetrazol-5-yl)-1H-1,2,4-triazol-5-yl)hydrazine salts

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Mar 2018, accepted on 26 Jul 2018 and first published on 26 Jul 2018


Article type: Letter
DOI: 10.1039/C8NJ01180J
Citation: New J. Chem., 2018, Advance Article
  •   Request permissions

    A novel facile transformation to 1,2-bis(3-nitro-1-(1H-tetrazol-5-yl)-1H-1,2,4-triazol-5-yl)hydrazine salts

    B. Zhao, X. Li, P. Wang, Y. Ding and Z. Zhou, New J. Chem., 2018, Advance Article , DOI: 10.1039/C8NJ01180J

Search articles by author

Spotlight

Advertisements