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Issue 14, 2018
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Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters

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Abstract

Ti6O6(OiPr)2(OOCR′)10 (R′ = C4H7, Et) and Ti6O3(OiPr)14(OOC–CH[double bond, length as m-dash]CH–COO)2 represent new structure types of carboxylate-substituted clusters with a Ti6Ox core (x = 3–6). They complement the already known six structure types and thus allow conclusions on how the structures of such clusters evolve during substitution and condensation processes.

Graphical abstract: Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters

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Publication details

The article was received on 08 Mar 2018, accepted on 19 Jun 2018 and first published on 19 Jun 2018


Article type: Paper
DOI: 10.1039/C8NJ01077C
Citation: New J. Chem., 2018,42, 12098-12103
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    Two new hexanuclear titanium oxo cluster types and their structural connection to known clusters

    M. Czakler, C. Artner and U. Schubert, New J. Chem., 2018, 42, 12098
    DOI: 10.1039/C8NJ01077C

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