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Issue 10, 2018
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Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

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Abstract

Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.

Graphical abstract: Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

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Publication details

The article was received on 17 Jan 2018, accepted on 06 Mar 2018 and first published on 07 Mar 2018


Article type: Paper
DOI: 10.1039/C8NJ00300A
Citation: New J. Chem., 2018,42, 8220-8229
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    Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

    X. Jiang, W. Shan, N. Desbois, V. Quesneau, S. Brandès, E. V. Caemelbecke, W. R. Osterloh, V. Blondeau-Patissier, C. P. Gros and K. M. Kadish, New J. Chem., 2018, 42, 8220
    DOI: 10.1039/C8NJ00300A

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