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Issue 7, 2018
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Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols

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Abstract

A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using “green”, commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).

Graphical abstract: Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols

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Publication details

The article was received on 06 Feb 2018, accepted on 22 Feb 2018 and first published on 28 Feb 2018


Article type: Communication
DOI: 10.1039/C8GC00424B
Citation: Green Chem., 2018,20, 1467-1471
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    Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols

    A. V. Arzumanyan, I. K. Goncharova, R. A. Novikov, S. A. Milenin, K. L. Boldyrev, P. N. Solyev, Y. V. Tkachev, A. D. Volodin, A. F. Smol'yakov, A. A. Korlyukov and A. M. Muzafarov, Green Chem., 2018, 20, 1467
    DOI: 10.1039/C8GC00424B

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