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Al3+ intercalation/de-intercalation-enabled dual-band electrochromic smart windows with a high optical modulation, quick response and long cycle life

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Abstract

Dual-band electrochromic smart windows with independent control of the transmittance of near-infrared (NIR) and visible (VIS) light can contribute significantly to the reduction of building energy consumption. Cost and inadequate electrochromic performance are the current technical challenges. We present here a dual-band electrochromic smart window design based on the intercalation/de-intercalation of Al3+ cations to replace the common use of monovalent cations in electrochromic applications. The Al3+ intercalation/de-intercalation-enabled electrochromic smart window delivers not only efficient and independent control of NIR and VIS light transmittance, but also impressive electrochromic performance – a high optical modulation of the full solar spectrum (93.2%, 91.7%, 88.5%, and 86.8% at 633, 800, 1200, and 1600 nm, respectively), high coloration efficiencies (254 and 121 cm2 C−1 at 1200 and 633 nm, respectively), fast switching times (8/5 s and 16/13 s at 1200 and 633 nm, respectively, for coloration/bleaching), and high bistability and cyclability (a 5.5% capacity loss after 2000 cycles). The good electrochromic performance can be attributed to the effective diffusion of Al3+ in the electrochromic material (as good as that of Li+); and a shallow intercalation/de-intercalation depth enabled by the ability of Al3+ to support three-electron redox reactions. The performance of Al3+ intercalation/de-intercalation-enabled dual-band electrochromism was also verified in laboratory prototype devices to confirm its suitability for dual-band smart windows.

Graphical abstract: Al3+ intercalation/de-intercalation-enabled dual-band electrochromic smart windows with a high optical modulation, quick response and long cycle life

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Publication details

The article was received on 13 Jun 2018, accepted on 31 Jul 2018 and first published on 01 Aug 2018


Article type: Paper
DOI: 10.1039/C8EE01718B
Citation: Energy Environ. Sci., 2018, Advance Article
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    Al3+ intercalation/de-intercalation-enabled dual-band electrochromic smart windows with a high optical modulation, quick response and long cycle life

    S. Zhang, S. Cao, T. Zhang, A. Fisher and J. Y. Lee, Energy Environ. Sci., 2018, Advance Article , DOI: 10.1039/C8EE01718B

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