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A non-innocent pincer H3LONS ligand and its corresponding octahedral low-spin Fe(III) complex formation via ligand-centric homolytic S–S bond scission

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Abstract

In the presence of FeCl3 and Et3N, a ligand H4Ldtda(AP) underwent S–S bond cleavage and generated a pincer non-innocent H3LONS ligand, which formed a homoleptic, six-coordinate, low-spin Fe(III) complex (1). The complex comprised two 2-iminobenzosemiquinone (1) π-radicals and one thiyl π-radical.

Graphical abstract: A non-innocent pincer H3LONS ligand and its corresponding octahedral low-spin Fe(iii) complex formation via ligand-centric homolytic S–S bond scission

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Publication details

The article was received on 06 Jul 2018, accepted on 29 Aug 2018 and first published on 29 Aug 2018


Article type: Communication
DOI: 10.1039/C8DT02763C
Citation: Dalton Trans., 2018, Advance Article
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    A non-innocent pincer H3LONS ligand and its corresponding octahedral low-spin Fe(III) complex formation via ligand-centric homolytic S–S bond scission

    P. Sarkar and C. Mukherjee, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT02763C

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