Jump to main content
Jump to site search

Issue 35, 2018
Previous Article Next Article

Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

Author affiliations

Abstract

Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn2(HPO3)2(BIP)]·H2O (1) and [Zn3(HPO3)3(BIP)(H2O)]·H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(II) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(II) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied.

Graphical abstract: Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Jul 2018, accepted on 15 Aug 2018 and first published on 16 Aug 2018


Article type: Paper
DOI: 10.1039/C8DT02761G
Citation: Dalton Trans., 2018,47, 12468-12473
  •   Request permissions

    Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

    S. Han, X. Zhang, J. Pan, Y. Mu, J. Li and G. Wang, Dalton Trans., 2018, 47, 12468
    DOI: 10.1039/C8DT02761G

Search articles by author

Spotlight

Advertisements