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Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

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Abstract

This paper describes our recent progress in catalytic nitrogen fixation using transition metal–dinitrogen complexes as catalysts. Our research group has recently developed novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and hydrazine using molybdenum–, iron–, cobalt– and vanadium–dinitrogen complexes under mild reaction conditions. The new findings presented in this paper may provide a new approach to the development of economical nitrogen fixation to replace the energy-consuming Haber–Bosch process.

Graphical abstract: Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

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Publication details

The article was received on 24 Jun 2018, accepted on 26 Jul 2018 and first published on 26 Jul 2018


Article type: Perspective
DOI: 10.1039/C8DT02572J
Citation: Dalton Trans., 2018, Advance Article
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    Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

    Y. Nishibayashi, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT02572J

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