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Protonation and water exchange kinetics in sandwich polyoxometalates

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Abstract

Density functional theory is used to explore the locus and consequences of protonation in [Zn4(HO)2(PW9O34)2]10−. The results are used to explain recent observations regarding the contrasting pH effects on the water-ligand exchange in [Mn4(H2O)2(P2W15O56)2]16− and [Co4(H2O)2(P2W15O56)2]16−, and the general effect of protonation on solvent exchange in metal oxides is discussed.

Graphical abstract: Protonation and water exchange kinetics in sandwich polyoxometalates

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Publication details

The article was received on 07 Jun 2018, accepted on 30 Aug 2018 and first published on 05 Sep 2018


Article type: Paper
DOI: 10.1039/C8DT02342E
Citation: Dalton Trans., 2018, Advance Article
  • Open access: Creative Commons BY-NC license
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    Protonation and water exchange kinetics in sandwich polyoxometalates

    C. A. Ohlin and M. Pascual-Borràs, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT02342E

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