Issue 34, 2018

Octacyanometallate qubit candidates

Abstract

We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3− and [W(CN)8]3−. At 5 K, these complexes display remarkably long spin–lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin–orbit coupling as a handle to tune vibrationally mediated spin–lattice relaxation.

Graphical abstract: Octacyanometallate qubit candidates

Supplementary files

Article information

Article type
Communication
Submitted
05 Jun 2018
Accepted
04 Jul 2018
First published
11 Jul 2018

Dalton Trans., 2018,47, 11744-11748

Author version available

Octacyanometallate qubit candidates

T. J. Pearson, D. W. Laorenza, M. D. Krzyaniak, M. R. Wasielewski and D. E. Freedman, Dalton Trans., 2018, 47, 11744 DOI: 10.1039/C8DT02312C

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