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Issue 27, 2018
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Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

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Abstract

Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C–C multiple bonds with primary phosphines under mild conditions. A broad range of alkenes and alkynes underwent a mono-addition reaction with phenylphosphine, which generated secondary phosphines in 39–99% yields and >7 : 1 selectivity (over double hydrophosphination).

Graphical abstract: Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

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Publication details

The article was received on 24 May 2018, accepted on 16 Jun 2018 and first published on 19 Jun 2018


Article type: Paper
DOI: 10.1039/C8DT02122H
Citation: Dalton Trans., 2018,47, 9090-9095
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    Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

    Y. Zhang, X. Wang, Y. Wang, D. Yuan and Y. Yao, Dalton Trans., 2018, 47, 9090
    DOI: 10.1039/C8DT02122H

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