Jump to main content
Jump to site search


Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

Author affiliations

Abstract

A trinuclear cyanide-bridged luminescent compound, trans-RuII(DMAP)4(CN)2[(PY5Me2)Mn]2[PF6]4 (1-R), and its oxidation product, ferromagnetic trans-RuIII(DMAP)4(CN)2[(PY5Me2)Mn]2-[PF6]5 (1-O), were synthesized and fully characterized. This is the first example of a molecular material showing a redox-controlled transformation between fluorescence and ferromagnetism.

Graphical abstract: Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 May 2018, accepted on 22 Jun 2018 and first published on 27 Jun 2018


Article type: Communication
DOI: 10.1039/C8DT01905C
Citation: Dalton Trans., 2018, Advance Article
  •   Request permissions

    Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

    X. Zhu, S. Su, Y. Wen, L. Zhang, Y. Yang, X. Wu and T. Sheng, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT01905C

Search articles by author

Spotlight

Advertisements