A vapochromic strategy for ammonia sensing based on a bipyridinium constructed porous framework

Cheng Chen; Huizhen Rao; Shen Lin; Jie Zhang

doi:10.1039/C8DT01728J

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A vapochromic strategy for ammonia sensing based on a bipyridinium constructed porous framework†

Cheng Chen,^abc Huizhen Rao,^a Shen Lin*^a and Jie Zhang

*^bc

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* Corresponding authors

^a College of Chemistry & Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, P. R. China
E-mail: shenlin@fjnu.edu.cn

^b MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, P. R. China
E-mail: zhangjie68@bit.edu.cn

^c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, Fujian 350002, P. R. China

Abstract

A new porous coordination polymer has been constructed based on a flexible bipyridinium derivative and iodine anions. The compound exhibits a rapid vapochromic response to ammonia molecules due to competitive complexation and an enhanced charge transfer effect.

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DOI: https://doi.org/10.1039/C8DT01728J
Article type: Communication
Submitted: 01 May 2018
Accepted: 02 Jun 2018
First published: 05 Jun 2018

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Dalton Trans., 2018,47, 8204-8208

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A vapochromic strategy for ammonia sensing based on a bipyridinium constructed porous framework

C. Chen, H. Rao, S. Lin and J. Zhang, Dalton Trans., 2018, 47, 8204 DOI: 10.1039/C8DT01728J

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Dalton Transactions

A vapochromic strategy for ammonia sensing based on a bipyridinium constructed porous framework†

Abstract

Supplementary files

Article information

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A vapochromic strategy for ammonia sensing based on a bipyridinium constructed porous framework

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