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Issue 31, 2018
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Crystalline, room-temperature stable phosphine–SO2 adducts: generation of sulfur monoxide from sulfur dioxide

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Abstract

The particularly basic phosphines 1a–c readily form isolable, zwitterionic Lewis base adducts with SO2 that were fully characterized including by X-ray diffraction studies. Computational and reactivity studies show that these adducts readily release SO at room temperature driven by the formation of the corresponding phosphine oxides.

Graphical abstract: Crystalline, room-temperature stable phosphine–SO2 adducts: generation of sulfur monoxide from sulfur dioxide

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Publication details

The article was received on 15 Apr 2018, accepted on 21 Jun 2018 and first published on 26 Jun 2018


Article type: Communication
DOI: 10.1039/C8DT01484A
Citation: Dalton Trans., 2018,47, 10420-10424
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    Crystalline, room-temperature stable phosphine–SO2 adducts: generation of sulfur monoxide from sulfur dioxide

    F. Buß, P. Rotering, C. Mück-Lichtenfeld and F. Dielmann, Dalton Trans., 2018, 47, 10420
    DOI: 10.1039/C8DT01484A

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