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Issue 27, 2018
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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

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Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

Graphical abstract: Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

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Publication details

The article was received on 13 Apr 2018, accepted on 07 May 2018 and first published on 10 May 2018


Article type: Paper
DOI: 10.1039/C8DT01455H
Citation: Dalton Trans., 2018,47, 8892-8896
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    Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

    M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892
    DOI: 10.1039/C8DT01455H

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