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Post-functionalization of a photoactive hybrid polyoxotungstate

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Abstract

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.

Graphical abstract: Post-functionalization of a photoactive hybrid polyoxotungstate

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Publication details

The article was received on 30 Mar 2018, accepted on 09 May 2018 and first published on 15 May 2018


Article type: Paper
DOI: 10.1039/C8DT01253A
Citation: Dalton Trans., 2018, Advance Article
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    Post-functionalization of a photoactive hybrid polyoxotungstate

    J. M. Cameron, S. Fujimoto, R. Wei, G. N. Newton and H. Oshio, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C8DT01253A

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