Jump to main content
Jump to site search

Issue 23, 2018
Previous Article Next Article

The first representatives of tetranuclear gold(I) complexes of P,N-containing cyclophanes

Author affiliations

Abstract

The first representatives of the tetranuclear gold(I) complexes of P,N-containing cyclophanes with two 1,5-diaza-3,7-diphosphacyclooctane rings incorporated into the macrocyclic core have been obtained. The complexation leads to a change in ligand conformations so that the diazadiphosphacyclooctane fragments of the complexes adopt twist-chair conformations, and two of the four gold(I) ions are located over and under the partially collapsed macrocyclic cavity. The complexes demonstrate moderate solid-state green emission.

Graphical abstract: The first representatives of tetranuclear gold(i) complexes of P,N-containing cyclophanes

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Mar 2018, accepted on 09 May 2018 and first published on 11 May 2018


Article type: Paper
DOI: 10.1039/C8DT01073K
Citation: Dalton Trans., 2018,47, 7715-7720
  •   Request permissions

    The first representatives of tetranuclear gold(I) complexes of P,N-containing cyclophanes

    Yu. A. Nikolaeva, A. S. Balueva, A. A. Khafizov, I. D. Strelnik, T. P. Gerasimova, S. A. Katsyuba, I. A. Litvinov, E. I. Musina, A. A. Karasik and O. G. Sinyashin, Dalton Trans., 2018, 47, 7715
    DOI: 10.1039/C8DT01073K

Search articles by author

Spotlight

Advertisements