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Gold-catalyzed glycosylation in the synthesis of complex carbohydrate-containing natural products

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Abstract

The methodological developments in gold(I)- and gold(III)-catalyzed glycosylation reactions are fully surveyed, which exploit the special alkynophilicity or the Lewis acidity of the gold cationic complexes. The application of the new methods in the total synthesis of naturally occurring glycoconjugates and glycans is comprehensively reviewed, with a focus on glycosylation of various complex aglycones.

Graphical abstract: Gold-catalyzed glycosylation in the synthesis of complex carbohydrate-containing natural products

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Publication details

The article was received on 19 Mar 2018 and first published on 11 Jul 2018


Article type: Review Article
DOI: 10.1039/C8CS00209F
Citation: Chem. Soc. Rev., 2018, Advance Article
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    Gold-catalyzed glycosylation in the synthesis of complex carbohydrate-containing natural products

    W. Li and B. Yu, Chem. Soc. Rev., 2018, Advance Article , DOI: 10.1039/C8CS00209F

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