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Copper-boryl mediated organic synthesis

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Abstract

Organoboron compounds are valuable synthetic intermediates that find application in a diverse variety of processes including both C–X and C–C bond-forming transformations. This has been achieved by using a variety of boron derivatives. Of these, boronate esters are probably the most versatile and, reflecting this, methods for the generation of boronate esters are of considerable current interest. Given the mild reaction conditions, good functional group tolerance, and low cost of the metal catalyst, the use of copper-boryl reagents is particularly attractive. In this review, methodologies in copper-boryl chemistry are discussed and the many different transformations possible are surveyed.

Graphical abstract: Copper-boryl mediated organic synthesis

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Publication details

The article was received on 30 Mar 2018 and first published on 12 Sep 2018


Article type: Review Article
DOI: 10.1039/C7CS00816C
Citation: Chem. Soc. Rev., 2018, Advance Article
  • Open access: Creative Commons BY license
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    Copper-boryl mediated organic synthesis

    D. Hemming, R. Fritzemeier, S. A. Westcott, W. L. Santos and P. G. Steel, Chem. Soc. Rev., 2018, Advance Article , DOI: 10.1039/C7CS00816C

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