Jump to main content
Jump to site search

Issue 31, 2018
Previous Article Next Article

An expanded MIL-53-type coordination polymer with a reactive pendant ligand

Author affiliations

Abstract

A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid-state NMR for this post-synthesis modification.

Graphical abstract: An expanded MIL-53-type coordination polymer with a reactive pendant ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 29 May 2018, accepted on 18 Jun 2018 and first published on 18 Jul 2018


Article type: Communication
DOI: 10.1039/C8CE00891D
Citation: CrystEngComm, 2018,20, 4355-4358
  • Open access: Creative Commons BY license
  •   Request permissions

    An expanded MIL-53-type coordination polymer with a reactive pendant ligand

    H. Kunicki, T. W. Chamberlain, G. J. Clarkson, R. J. Kashtiban, J. E. Hooper, D. M. Dawson, S. E. Ashbrook and R. I. Walton, CrystEngComm, 2018, 20, 4355
    DOI: 10.1039/C8CE00891D

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements