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Issue 32, 2018
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Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

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Abstract

A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(II) gave IMP-20 and with Zn(II) gave IMP-21: both are 3D MOFs incorporating Si–O–Si–O–Si linkages.

Graphical abstract: Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

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Publication details

The article was received on 25 Apr 2018, accepted on 22 Jun 2018 and first published on 02 Aug 2018


Article type: Communication
DOI: 10.1039/C8CE00662H
Citation: CrystEngComm, 2018,20, 4541-4545
  • Open access: Creative Commons BY license
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    Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

    L. C. Delmas, A. J. P. White, D. Pugh, P. N. Horton, S. J. Coles, P. D. Lickiss and R. P. Davies, CrystEngComm, 2018, 20, 4541
    DOI: 10.1039/C8CE00662H

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