Synthesis of an ultra-stable metal–organic framework for proton conduction

Chuanfang Liu; Nian Zhao; Xiaoqin Zou; Guangshan Zhu

doi:10.1039/C8CE00564H

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Synthesis of an ultra-stable metal–organic framework for proton conduction†

Chuanfang Liu,^a Nian Zhao,

^b Xiaoqin Zou

*^a and Guangshan Zhu^a

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* Corresponding authors

^a Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
E-mail: zouxq100@nenu.edu.cn

^b Institute for Advanced Materials, Hubei Normal University, Huangshi 435002, P. R. China

Abstract

A new ultra-stable metal–organic framework of Zn₃(IBT)₂(H₂O)₂ is synthesized. This MOF not only exhibits good thermal stability but also shows superior chemical stability in terms of water resistance, acid/base tolerance and solvent anticorrosion. In addition, it shows moderate proton-conductive properties with a conductivity of 1.98 × 10⁻⁵ S cm⁻¹ at ∼30 °C and 97% RH.

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DOI: https://doi.org/10.1039/C8CE00564H
Article type: Communication
Submitted: 10 Apr 2018
Accepted: 10 May 2018
First published: 11 May 2018

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CrystEngComm, 2018,20, 3158-3161

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Synthesis of an ultra-stable metal–organic framework for proton conduction

C. Liu, N. Zhao, X. Zou and G. Zhu, CrystEngComm, 2018, 20, 3158 DOI: 10.1039/C8CE00564H

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CrystEngComm

Synthesis of an ultra-stable metal–organic framework for proton conduction†

Abstract

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Synthesis of an ultra-stable metal–organic framework for proton conduction

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