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A uranyl phosphonate framework with a temperature-induced order–disorder transition and temperature-correlated photoluminescence

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Abstract

A uranyl phosphonate framework, (UO2)2(1,3-pbp)(H2O)2·2H2O (UPF-1) (1,3-pbp = 1,3-phenylenebis(phosphonic acid)), experiences a thermally induced order–disorder transition, leading to a negative linear correlation between the photoluminescence intensity and temperature, and may find application as a luminescent thermometer.

Graphical abstract: A uranyl phosphonate framework with a temperature-induced order–disorder transition and temperature-correlated photoluminescence

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Publication details

The article was received on 23 Mar 2018, accepted on 20 Apr 2018 and first published on 21 Apr 2018


Article type: Communication
DOI: 10.1039/C8CE00450A
Citation: CrystEngComm, 2018, Advance Article
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    A uranyl phosphonate framework with a temperature-induced order–disorder transition and temperature-correlated photoluminescence

    Y. Wang, X. Wang, D. Zhang, F. Zhou, D. Gui, T. Zheng, J. Li, Z. Chai and S. Wang, CrystEngComm, 2018, Advance Article , DOI: 10.1039/C8CE00450A

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