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Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole

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Abstract

Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids. Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state [2 + 2] cycloaddition reaction.

Graphical abstract: Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole

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Publication details

The article was received on 22 Mar 2018, accepted on 08 Jun 2018 and first published on 08 Jun 2018


Article type: Communication
DOI: 10.1039/C8CE00447A
Citation: CrystEngComm, 2018, Advance Article
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    Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole

    A. L. Grobelny, N. P. Rath and R. H. Groeneman, CrystEngComm, 2018, Advance Article , DOI: 10.1039/C8CE00447A

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