Issue 78, 2018
From the journal:

Chemical Communications

Hydrogen bond directed aerobic oxidation of amines via photoredox catalysis†

Hongyu Wang,‡*a   Yunquan Man,‡a   Kaiye Wang,a   Xiuyan Wan,a   Lili Tong,a   Na Li ORCID logo a  and  Bo Tang ORCID logo *a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Institute of Molecular and Nano Science, Shandong Normal University, Jinan 250014, P. R. China
E-mail: tangb@sdnu.edu.cn, wanghongyu@sdnu.edu.cn

Abstract

An application of H-bonding interactions for directing the α-C–H oxidation of amines to amides and amino-ketones catalyzed by an organic photocatalyst is reported. The high efficiency of this method is demonstrated by the aerobic oxidation of pyrrolidines, diarylamines and benzylamines bearing urea groups with high yields and a wide substrate scope.

Graphical abstract: Hydrogen bond directed aerobic oxidation of amines via photoredox catalysis

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Article information

DOI
https://doi.org/10.1039/C8CC06603E
Article type
Communication
Submitted
13 Aug 2018
Accepted
04 Sep 2018
First published
04 Sep 2018

Chem. Commun., 2018,54, 10989-10992

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Hydrogen bond directed aerobic oxidation of amines via photoredox catalysis

H. Wang, Y. Man, K. Wang, X. Wan, L. Tong, N. Li and B. Tang, Chem. Commun., 2018, 54, 10989 DOI: 10.1039/C8CC06603E

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