Jump to main content
Jump to site search


Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

Author affiliations

Abstract

Reaction of the first homoleptic U(III) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(III) to U(V) and isolation of a U(V) hydrazido complex. Corresponding U(V) imido, U(V) oxo, and U(IV) azido complexes were also synthesized for structural comparison.

Graphical abstract: Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Aug 2018, accepted on 06 Sep 2018 and first published on 12 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06514D
Citation: Chem. Commun., 2018, Advance Article
  •   Request permissions

    Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

    N. S. Settineri, A. A. Shiau and J. Arnold, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC06514D

Search articles by author

Spotlight

Advertisements