Issue 78, 2018

Metallaaromatic biaryl atropisomers

Abstract

Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1′-binaphthalene both in terms of aromaticity and atropisomerism.

Graphical abstract: Metallaaromatic biaryl atropisomers

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2018
Accepted
06 Sep 2018
First published
07 Sep 2018

Chem. Commun., 2018,54, 10974-10976

Metallaaromatic biaryl atropisomers

M. Talavera, A. Peña-Gallego, J. L. Alonso-Gómez and S. Bolaño, Chem. Commun., 2018, 54, 10974 DOI: 10.1039/C8CC06443A

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