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Conjugate addition from the excited state

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Abstract

Conjugate addition occurs efficiently from excited hydrazide based acrylanilides under both UV and metal free visible light irradiations. The reaction proceeds via an excited state encounter complex that bifurcates either via an electron or energy transfer pathway. The generality of excited state conjugate addition is demonstrated using chloromethylation and by thiol addition.

Graphical abstract: Conjugate addition from the excited state

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Publication details

The article was received on 21 Jul 2018, accepted on 04 Sep 2018 and first published on 04 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC05924A
Citation: Chem. Commun., 2018, Advance Article
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    Conjugate addition from the excited state

    A. Iyer, S. Ahuja, S. Jockusch, A. Ugrinov and J. Sivaguru, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC05924A

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