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Cofacial porphyrin dimers assembled from N-heterocyclic carbene–metal bonds

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Abstract

A porphyrin bearing four imidazolium rings on the meso positions was used as an N-heterocyclic carbene (NHC) precursor for the synthesis of porphyrin dimers with face-to-face orientations. The porphyrins are connected through the formation of eight M–CNHC bonds, with M = AgI or AuI.

Graphical abstract: Cofacial porphyrin dimers assembled from N-heterocyclic carbene–metal bonds

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Publication details

The article was received on 14 Jul 2018, accepted on 01 Aug 2018 and first published on 02 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05707A
Citation: Chem. Commun., 2018, Advance Article
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    Cofacial porphyrin dimers assembled from N-heterocyclic carbene–metal bonds

    C. Rose, A. Lebrun, S. Clément and S. Richeter, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC05707A

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