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Rhodium(II)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans

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Abstract

Donor–acceptor cyclopropenes formed from enoldiazoketones undergo catalytic rearrangement to 5-aryl-2-siloxyfurans via a novel mechanism that involves a nucleophilic addition of the carbonyl oxygen to the rhodium-activated cyclopropene.

Graphical abstract: Rhodium(ii)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans

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Publication details

The article was received on 11 Jul 2018, accepted on 30 Jul 2018 and first published on 02 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05623D
Citation: Chem. Commun., 2018, Advance Article
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    Rhodium(II)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans

    K. O. Marichev, Y. Wang, A. M. Carranco, E. C. Garcia, Z. Yu and M. P. Doyle, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC05623D

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