Jump to main content
Jump to site search

Issue 77, 2018
Previous Article Next Article

Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

Author affiliations

Abstract

The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp22− (PyCp22− = [2,6-(CH2C5H3)2C5H3N]2−) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce–Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy–Fe bonded species.

Graphical abstract: Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

Back to tab navigation

Supplementary files

Publication details

The article was received on 02 Jul 2018, accepted on 04 Sep 2018 and first published on 04 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC05243C
Citation: Chem. Commun., 2018,54, 10893-10896
  •   Request permissions

    Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

    C. P. Burns, X. Yang, S. Sung, J. D. Wofford, N. S. Bhuvanesh, M. B. Hall and M. Nippe, Chem. Commun., 2018, 54, 10893
    DOI: 10.1039/C8CC05243C

Search articles by author

Spotlight

Advertisements