Issue 62, 2018
From the journal:

Chemical Communications

Flow chemistry-enabled studies of rhodium-catalyzed hydroformylation reactions†

Cheng Zhu,a   Keshav Raghuvanshi, ORCID logo a   Connor W. Coley, ORCID logo b   Dawn Mason,c   Jody Rodgers,c   Mesfin E. Jankac  and  Milad Abolhasani ORCID logo *a  

* Corresponding authors

a Department of Chemical and Biomolecular Engineering, North Carolina State University, 911 Partners Way, Raleigh, NC 27695, USA
E-mail: abolhasani@ncsu.edu

b Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA

c Eastman Chemical Company, 200 S. Wilcox Dr., Kingsport, TN 37660, USA

Abstract

We present an automated microscale flow chemistry platform for rapid performance evaluation of continuous and discrete reaction parameters in homogeneous hydroformylation reactions. We demonstrate the versatility of the developed microfluidic platform through a systematic study of the effects of a library of phosphine-based ligands on catalytic activity and regioselectivity.

Graphical abstract: Flow chemistry-enabled studies of rhodium-catalyzed hydroformylation reactions

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Article information

DOI
https://doi.org/10.1039/C8CC04650F
Article type
Communication
Submitted
12 Jun 2018
Accepted
03 Jul 2018
First published
03 Jul 2018

Chem. Commun., 2018,54, 8567-8570

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Flow chemistry-enabled studies of rhodium-catalyzed hydroformylation reactions

C. Zhu, K. Raghuvanshi, C. W. Coley, D. Mason, J. Rodgers, M. E. Janka and M. Abolhasani, Chem. Commun., 2018, 54, 8567 DOI: 10.1039/C8CC04650F

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