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Issue 65, 2018
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A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal–organic framework

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Abstract

We report the application of a post-synthetic solid-state cation-exchange process to afford a novel 3D MOF with hydrated barium cations hosted at pores able to trigger selective and reversible SO2 adsorption. Computational modelling supports the full reversibility of the adsorption process on the basis of weak supramolecular interactions between SO2 and coordinated water molecules.

Graphical abstract: A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal–organic framework

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Publication details

The article was received on 05 Jun 2018, accepted on 23 Jul 2018 and first published on 23 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC04482A
Citation: Chem. Commun., 2018,54, 9063-9066
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    A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal–organic framework

    M. Mon, E. Tiburcio, J. Ferrando-Soria, R. Gil San Millán, J. A. R. Navarro, D. Armentano and E. Pardo, Chem. Commun., 2018, 54, 9063
    DOI: 10.1039/C8CC04482A

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