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Issue 49, 2018
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Synthesis of Rh(III) thiophosphinito pincer hydrido complexes by base-free C–H bond activation at room temperature

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Abstract

Rhodium(III) thiophosphinito pincer hydrido complexes were synthesised by C–H activation under exceptionally mild conditions at room temperature without additional base or irradiation and fully characterised by multinuclear NMR spectroscopy and X-ray crystallography. C–H activation under these mild conditions contrasts with the reactivity of related systems with POCOP ligands.

Graphical abstract: Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C–H bond activation at room temperature

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Publication details

The article was received on 16 May 2018, accepted on 25 May 2018 and first published on 25 May 2018


Article type: Communication
DOI: 10.1039/C8CC03913E
Citation: Chem. Commun., 2018,54, 6292-6295
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    Synthesis of Rh(III) thiophosphinito pincer hydrido complexes by base-free C–H bond activation at room temperature

    G. Vlahopoulou, S. Möller, J. Haak, P. Hasche, H.-J. Drexler, D. Heller and T. Beweries, Chem. Commun., 2018, 54, 6292
    DOI: 10.1039/C8CC03913E

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