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Dual Electrical Switching Permeability of Vesicles via Redox-Responsive Self-Assembly of Amphiphilic Block Copolymers and Polyoxometalates

Abstract

Eletro-responsive vesicles were recently demonstrated based on an amphiphilic block copolymer PEO114-b-P(DCH-Ru)n and an inorganic nanoparticle polyoxometalate H3PMo12O40 (PMo12) via electrostatic interactions. After undergoing electrochemical reactions, vesicle membranes allow the migration of electrolyte ions and release of loaded cargos. Well-organized layerd nanostructures have a remarkable effect on the optical modulation in the film casting from the vesicular solution.

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Publication details

The article was received on 09 May 2018, accepted on 13 Jun 2018 and first published on 14 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03749C
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Dual Electrical Switching Permeability of Vesicles via Redox-Responsive Self-Assembly of Amphiphilic Block Copolymers and Polyoxometalates

    D. Chong, J. Tan, J. Zhang, Y. Zhou, X. Wan and J. Zhang, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC03749C

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