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Issue 49, 2018
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Highly efficient temperature-dependent chiral separation with a nucleotide-based coordination polymer

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Abstract

We report a new chiral coordination polymer, prepared from the cytidine 5′-monophosphate (CMP) nucleotide, capable of separating efficiently (enantiomeric excess of ca. 100%) racemic mixtures of L- and D-Asp in a temperature-dependent manner. The crystal structure of the host–guest adsorbate, with the D-Asp guest molecules loaded within its channels, could be solved allowing a direct visualization of the chiral recognition process.

Graphical abstract: Highly efficient temperature-dependent chiral separation with a nucleotide-based coordination polymer

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Publication details

The article was received on 02 May 2018, accepted on 29 May 2018 and first published on 29 May 2018


Article type: Communication
DOI: 10.1039/C8CC03544J
Citation: Chem. Commun., 2018,54, 6356-6359
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    Highly efficient temperature-dependent chiral separation with a nucleotide-based coordination polymer

    R. Bruno, N. Marino, L. Bartella, L. Di Donna, G. De Munno, E. Pardo and D. Armentano, Chem. Commun., 2018, 54, 6356
    DOI: 10.1039/C8CC03544J

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