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Issue 49, 2018
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Ytterbium and silver co-catalyzed synthesis of pyrrole-fused bicyclic skeletons from enynones and isocyanides

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Abstract

An unusual cascade reaction of isocyanide and enynone using Yb/Ag cooperative catalysis as a key step has been disclosed. The present strategy enables the double isocyanide insertion and subsequent 5-endo-dig cyclization, thus providing a quick access to structurally complex pyrrole-fused heterocycles.

Graphical abstract: Ytterbium and silver co-catalyzed synthesis of pyrrole-fused bicyclic skeletons from enynones and isocyanides

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Publication details

The article was received on 29 Apr 2018, accepted on 30 May 2018 and first published on 30 May 2018


Article type: Communication
DOI: 10.1039/C8CC03475C
Citation: Chem. Commun., 2018,54, 6412-6415
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    Ytterbium and silver co-catalyzed synthesis of pyrrole-fused bicyclic skeletons from enynones and isocyanides

    F. Li, P. Hu, M. Sun, C. Li, X. Jia and J. Li, Chem. Commun., 2018, 54, 6412
    DOI: 10.1039/C8CC03475C

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