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Issue 49, 2018
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Highly enantioselective Friedel–Crafts alkylation of N,N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal–organic framework

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Abstract

The first enantioselective Friedel–Crafts alkylation of N,N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal–organic framework constructed from (R)-2,2′-dihydroxy-1,1′-binaphthyl-6,6′-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) with excellent enantioselectivities (∼98% ee).

Graphical abstract: Highly enantioselective Friedel–Crafts alkylation of N,N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal–organic framework

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Publication details

The article was received on 28 Apr 2018, accepted on 24 May 2018 and first published on 25 May 2018


Article type: Communication
DOI: 10.1039/C8CC03447H
Citation: Chem. Commun., 2018,54, 6328-6331
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    Highly enantioselective Friedel–Crafts alkylation of N,N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal–organic framework

    K. Tanaka, K. Sakuragi, H. Ozaki and Y. Takada, Chem. Commun., 2018, 54, 6328
    DOI: 10.1039/C8CC03447H

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