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Issue 48, 2018
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Enantioselective total synthesis of sagittacin E and related natural products

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Abstract

The first enantioselective total synthesis of eremophilane-type sesquiterpenoids, sagittacin E and related natural products, was achieved. This synthesis features an asymmetric desymmetrization by Shi asymmetric epoxidation, intramolecular aldol-type cyclization, allylic oxidation of a 1,4-diene compound, and stereoselective epoxidation.

Graphical abstract: Enantioselective total synthesis of sagittacin E and related natural products

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Publication details

The article was received on 27 Apr 2018, accepted on 23 May 2018 and first published on 29 May 2018


Article type: Communication
DOI: 10.1039/C8CC03438A
Citation: Chem. Commun., 2018,54, 6165-6168
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    Enantioselective total synthesis of sagittacin E and related natural products

    H. Abe, M. Fujimaki, E. Nakagawa, T. Kobayashi and H. Ito, Chem. Commun., 2018, 54, 6165
    DOI: 10.1039/C8CC03438A

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