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Issue 57, 2018
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An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

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Abstract

Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.

Graphical abstract: An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

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Publication details

The article was received on 27 Apr 2018, accepted on 15 Jun 2018 and first published on 19 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03431A
Citation: Chem. Commun., 2018,54, 7979-7982
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    An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

    H. Liu, D. Yang, D. Wang, P. Wang, Y. Lu, V. Giang and Y. Liu, Chem. Commun., 2018, 54, 7979
    DOI: 10.1039/C8CC03431A

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